15-3914-0241. A base could accelerate the SN2′ or SN2′−SN2′ reaction of Morita−Baylis−Hillman (MBH) carbonates with dialkyl phosphine oxides, but the judicial choice of an appropriate base would greatly depress this competitive SN2′ reaction and allow for a highly enantioselective allylic substitution reaction with satisfactory yields and excellent enantioselectivities. 15-3914-0241

 
A base could accelerate the SN2′ or SN2′−SN2′ reaction of Morita−Baylis−Hillman (MBH) carbonates with dialkyl phosphine oxides, but the judicial choice of an appropriate base would greatly depress this competitive SN2′ reaction and allow for a highly enantioselective allylic substitution reaction with satisfactory yields and excellent enantioselectivities15-3914-0241  6

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